BTAMI: a core-twisted quaterrylene
Chemical structure of a chromophore in the form of a quaterrylene derivative featuring peripheral tert-butyl (–C(CH3)3) substituents and sterically hindering, core-anchored triflate groups (–O–SO2CF3). This unique core-twisted rylene strongly absorbs in the visible region and interestingly, presents a phosphorescence far in the near infra-red spectral region [1].
In the above model, the brown balls represent sulfur atoms, the red balls represent oxygen, the purple balls represent fluorine atoms. Carbon is represented in green and hydrogen in black.
- "A twisted bay-substituted quaterrylene phosphorescing in the NIR spectral region" T. Miletić, A. Fermi,I. Papadakis, I. Orfanos, N. Karampitsos, A. Avramopoulos,N. Demitri, F. De Leo, S.J.A. Pope, M.G. Papadopoulos, S. Couris, and D. Bonifazi, Helv. Chim. Acta 100 (2017) e1700192 [DOI: 10.1002/hlca.201700192]. .